Finding the perfect match: Halogen vs hydrogen bonding

Tanya Shirman; Meital Boterashvili; Meital Orbach; Dalia Freeman; L. J. W. Shimon; Michal Lahav; Milko E van der Boom

doi:10.1021/acs.cgd.5b01260

Finding the perfect match: Halogen vs hydrogen bonding

Tanya Shirman, Meital Boterashvili, Meital Orbach, Dalia Freeman, L. J. W. Shimon, Michal Lahav, Milko E van der Boom

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

Abstract

The prediction of supramolecular structures involving different weak interactions is challenging. In this study, single-atom modifications to the molecular structure allow us to address their hierarchy. The resulting series of unimolecular assemblies are mainly based on halogen bonding (XB), hydrogen bonding (HB), or a combination of both. By varying the XB donor (F, Cl, Br, and I) and the XB and HB acceptors (pyridine vs pyridine-N-oxide) we can control the primary motifs directing the structure.

Original language	English
Pages (from-to)	4756-4759
Number of pages	4
Journal	Crystal Growth and Design
Volume	15
Issue number	10
DOIs	https://doi.org/10.1021/acs.cgd.5b01260
State	Published - 7 Oct 2015

All Science Journal Classification (ASJC) codes

General Chemistry
Condensed Matter Physics
General Materials Science

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10.1021/acs.cgd.5b01260

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title = "Finding the perfect match: Halogen vs hydrogen bonding",

abstract = "The prediction of supramolecular structures involving different weak interactions is challenging. In this study, single-atom modifications to the molecular structure allow us to address their hierarchy. The resulting series of unimolecular assemblies are mainly based on halogen bonding (XB), hydrogen bonding (HB), or a combination of both. By varying the XB donor (F, Cl, Br, and I) and the XB and HB acceptors (pyridine vs pyridine-N-oxide) we can control the primary motifs directing the structure.",

author = "Tanya Shirman and Meital Boterashvili and Meital Orbach and Dalia Freeman and Shimon, {L. J. W.} and Michal Lahav and {van der Boom}, {Milko E}",

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T2 - Halogen vs hydrogen bonding

AU - Shirman, Tanya

AU - Boterashvili, Meital

AU - Orbach, Meital

AU - Freeman, Dalia

AU - Shimon, L. J. W.

AU - Lahav, Michal

AU - van der Boom, Milko E

PY - 2015/10/7

Y1 - 2015/10/7

N2 - The prediction of supramolecular structures involving different weak interactions is challenging. In this study, single-atom modifications to the molecular structure allow us to address their hierarchy. The resulting series of unimolecular assemblies are mainly based on halogen bonding (XB), hydrogen bonding (HB), or a combination of both. By varying the XB donor (F, Cl, Br, and I) and the XB and HB acceptors (pyridine vs pyridine-N-oxide) we can control the primary motifs directing the structure.

AB - The prediction of supramolecular structures involving different weak interactions is challenging. In this study, single-atom modifications to the molecular structure allow us to address their hierarchy. The resulting series of unimolecular assemblies are mainly based on halogen bonding (XB), hydrogen bonding (HB), or a combination of both. By varying the XB donor (F, Cl, Br, and I) and the XB and HB acceptors (pyridine vs pyridine-N-oxide) we can control the primary motifs directing the structure.

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U2 - 10.1021/acs.cgd.5b01260

DO - 10.1021/acs.cgd.5b01260

M3 - مقالة

SN - 1528-7483

VL - 15

SP - 4756

EP - 4759

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 10

ER -

Finding the perfect match: Halogen vs hydrogen bonding

Abstract

All Science Journal Classification (ASJC) codes

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