Evidence for metal-ligand cooperation in a Pd-PNF pincer-catalyzed cross-coupling

Adam Scharf; Israel Goldberg; Arkadi Vigalok

doi:10.1021/ja310782k

Evidence for metal-ligand cooperation in a Pd-PNF pincer-catalyzed cross-coupling

Adam Scharf, Israel Goldberg, Arkadi Vigalok

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

The first Pd-pincer complex bearing a halogen (fluorine) arm has been prepared via the base-assisted dearomatization of a phosphine-quinoline (P∼N) ligand. This dearomatization is reversible and has been used to facilitate catalytic Sonogashira-type cross-coupling that, contrary to the typical mechanistic approach, is based on a metal-ligand cooperation mode.

Original language	English
Pages (from-to)	967-970
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	3
DOIs	https://doi.org/10.1021/ja310782k
State	Published - 23 Jan 2013

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja310782k

Cite this

@article{07bf27f19633401c8b66c7ebd7f37655,

title = "Evidence for metal-ligand cooperation in a Pd-PNF pincer-catalyzed cross-coupling",

abstract = "The first Pd-pincer complex bearing a halogen (fluorine) arm has been prepared via the base-assisted dearomatization of a phosphine-quinoline (P∼N) ligand. This dearomatization is reversible and has been used to facilitate catalytic Sonogashira-type cross-coupling that, contrary to the typical mechanistic approach, is based on a metal-ligand cooperation mode.",

author = "Adam Scharf and Israel Goldberg and Arkadi Vigalok",

year = "2013",

month = jan,

day = "23",

doi = "10.1021/ja310782k",

language = "الإنجليزيّة",

volume = "135",

pages = "967--970",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Evidence for metal-ligand cooperation in a Pd-PNF pincer-catalyzed cross-coupling

AU - Scharf, Adam

AU - Goldberg, Israel

AU - Vigalok, Arkadi

PY - 2013/1/23

Y1 - 2013/1/23

N2 - The first Pd-pincer complex bearing a halogen (fluorine) arm has been prepared via the base-assisted dearomatization of a phosphine-quinoline (P∼N) ligand. This dearomatization is reversible and has been used to facilitate catalytic Sonogashira-type cross-coupling that, contrary to the typical mechanistic approach, is based on a metal-ligand cooperation mode.

AB - The first Pd-pincer complex bearing a halogen (fluorine) arm has been prepared via the base-assisted dearomatization of a phosphine-quinoline (P∼N) ligand. This dearomatization is reversible and has been used to facilitate catalytic Sonogashira-type cross-coupling that, contrary to the typical mechanistic approach, is based on a metal-ligand cooperation mode.

UR - http://www.scopus.com/inward/record.url?scp=84872800389&partnerID=8YFLogxK

U2 - 10.1021/ja310782k

DO - 10.1021/ja310782k

M3 - مقالة

SN - 0002-7863

VL - 135

SP - 967

EP - 970

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 3

ER -

Evidence for metal-ligand cooperation in a Pd-PNF pincer-catalyzed cross-coupling

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this