Electrocatalytic oxygen evolution reaction (OER) on mixed nanoporous RuIr borides

Saad Intikhab; Maxim Sokol; Varun Natu; Swarnendu Chatterjee; Yawei Li; Michel W. Barsoum; Joshua Snyder

doi:https://doi.org/10.1007/s10800-021-01555-z

Electrocatalytic oxygen evolution reaction (OER) on mixed nanoporous RuIr borides

Saad Intikhab, Maxim Sokol, Varun Natu, Swarnendu Chatterjee, Yawei Li, Michel W. Barsoum, Joshua Snyder

Research output: Contribution to journal › Article › peer-review

Abstract

Efficient water splitting for commercial electrolysis devices is predicated on the development of materials, specifically for the catalytic electrodes, that exhibit an optimal balance between activity and stability. Complicating the development of electrocatalytic materials, particularly for oxygen-evolving anodes in acidic polymer electrolyte membrane electrolyzers, is an inverse relationship between activity and stability. Here the development of a nanostructured oxygen evolution reaction (OER) electrocatalyst for low-pH water splitting is demonstrated. Dealloying of mixed RuIr borides is used to form a high aspect ratio electrocatalytic material that exhibits low OER overpotentials matching that of RuO_x and electrolytic stability matching that of IrO_x. Graphic abstract: [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	1101-1108
Number of pages	8
Journal	Journal of Applied Electrochemistry
Volume	51
Issue number	7
DOIs	https://doi.org/10.1007/s10800-021-01555-z
State	Published - 1 Jul 2021
Externally published	Yes

Keywords

Dealloying
Nanoporous metals
Oxygen evolution reaction
PEM electrolysis

All Science Journal Classification (ASJC) codes

General Chemical Engineering
Materials Chemistry
Electrochemistry

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https://doi.org/10.1007/s10800-021-01555-z

Cite this

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title = "Electrocatalytic oxygen evolution reaction (OER) on mixed nanoporous RuIr borides",

abstract = "Efficient water splitting for commercial electrolysis devices is predicated on the development of materials, specifically for the catalytic electrodes, that exhibit an optimal balance between activity and stability. Complicating the development of electrocatalytic materials, particularly for oxygen-evolving anodes in acidic polymer electrolyte membrane electrolyzers, is an inverse relationship between activity and stability. Here the development of a nanostructured oxygen evolution reaction (OER) electrocatalyst for low-pH water splitting is demonstrated. Dealloying of mixed RuIr borides is used to form a high aspect ratio electrocatalytic material that exhibits low OER overpotentials matching that of RuOx and electrolytic stability matching that of IrOx. Graphic abstract: [Figure not available: see fulltext.].",

keywords = "Dealloying, Nanoporous metals, Oxygen evolution reaction, PEM electrolysis",

author = "Saad Intikhab and Maxim Sokol and Varun Natu and Swarnendu Chatterjee and Yawei Li and Barsoum, {Michel W.} and Joshua Snyder",

note = "Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to Springer Nature B.V.",

year = "2021",

month = jul,

day = "1",

doi = "https://doi.org/10.1007/s10800-021-01555-z",

language = "الإنجليزيّة",

volume = "51",

pages = "1101--1108",

journal = "Journal of Applied Electrochemistry",

issn = "0021-891X",

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TY - JOUR

T1 - Electrocatalytic oxygen evolution reaction (OER) on mixed nanoporous RuIr borides

AU - Intikhab, Saad

AU - Sokol, Maxim

AU - Natu, Varun

AU - Chatterjee, Swarnendu

AU - Li, Yawei

AU - Barsoum, Michel W.

AU - Snyder, Joshua

PY - 2021/7/1

Y1 - 2021/7/1

N2 - Efficient water splitting for commercial electrolysis devices is predicated on the development of materials, specifically for the catalytic electrodes, that exhibit an optimal balance between activity and stability. Complicating the development of electrocatalytic materials, particularly for oxygen-evolving anodes in acidic polymer electrolyte membrane electrolyzers, is an inverse relationship between activity and stability. Here the development of a nanostructured oxygen evolution reaction (OER) electrocatalyst for low-pH water splitting is demonstrated. Dealloying of mixed RuIr borides is used to form a high aspect ratio electrocatalytic material that exhibits low OER overpotentials matching that of RuOx and electrolytic stability matching that of IrOx. Graphic abstract: [Figure not available: see fulltext.].

AB - Efficient water splitting for commercial electrolysis devices is predicated on the development of materials, specifically for the catalytic electrodes, that exhibit an optimal balance between activity and stability. Complicating the development of electrocatalytic materials, particularly for oxygen-evolving anodes in acidic polymer electrolyte membrane electrolyzers, is an inverse relationship between activity and stability. Here the development of a nanostructured oxygen evolution reaction (OER) electrocatalyst for low-pH water splitting is demonstrated. Dealloying of mixed RuIr borides is used to form a high aspect ratio electrocatalytic material that exhibits low OER overpotentials matching that of RuOx and electrolytic stability matching that of IrOx. Graphic abstract: [Figure not available: see fulltext.].

KW - Dealloying

KW - Nanoporous metals

KW - Oxygen evolution reaction

KW - PEM electrolysis

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U2 - https://doi.org/10.1007/s10800-021-01555-z

DO - https://doi.org/10.1007/s10800-021-01555-z

M3 - مقالة

SN - 0021-891X

VL - 51

SP - 1101

EP - 1108

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 7

ER -

Electrocatalytic oxygen evolution reaction (OER) on mixed nanoporous RuIr borides

Abstract

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

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