Dehydrogenative cross-coupling of primary and secondary alcohols

Sanaa Musa; Lutz Ackermann; Dmitri Gelman

doi:10.1002/adsc.201300656

Dehydrogenative cross-coupling of primary and secondary alcohols

Sanaa Musa, Lutz Ackermann, Dmitri Gelman

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.

Original language	English
Pages (from-to)	3077-3080
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	355
Issue number	14-15
DOIs	https://doi.org/10.1002/adsc.201300656
State	Published - 11 Oct 2013

Keywords

Acceptorless dehydrogenation
Crosscoupling
Innocent ligands
Ligand-metal cooperation
Pincer ligands

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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10.1002/adsc.201300656

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title = "Dehydrogenative cross-coupling of primary and secondary alcohols",

abstract = "Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.",

keywords = "Acceptorless dehydrogenation, Crosscoupling, Innocent ligands, Ligand-metal cooperation, Pincer ligands",

author = "Sanaa Musa and Lutz Ackermann and Dmitri Gelman",

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doi = "10.1002/adsc.201300656",

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T1 - Dehydrogenative cross-coupling of primary and secondary alcohols

AU - Musa, Sanaa

AU - Ackermann, Lutz

AU - Gelman, Dmitri

PY - 2013/10/11

Y1 - 2013/10/11

N2 - Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.

AB - Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.

KW - Acceptorless dehydrogenation

KW - Crosscoupling

KW - Innocent ligands

KW - Ligand-metal cooperation

KW - Pincer ligands

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U2 - 10.1002/adsc.201300656

DO - 10.1002/adsc.201300656

M3 - مقالة

SN - 1615-4150

VL - 355

SP - 3077

EP - 3080

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 14-15

ER -

Dehydrogenative cross-coupling of primary and secondary alcohols

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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