Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst

Kobi Oded, Sanaa Musa, Dmitri Gelman, Jochanan Blum

Research output: Contribution to journalArticlepeer-review

Abstract

We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.

Original languageEnglish
Pages (from-to)68-70
Number of pages3
JournalCatalysis Communications
Volume20
DOIs
StatePublished - 5 Apr 2012

Keywords

  • Acceptorless dehydrogenation
  • Iridium
  • Sol-gel processes
  • sp -Metalated pincer complex

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Process Chemistry and Technology
  • Catalysis

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