Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Smadar Attia; Alexander Shames; Israel Zilbermann; Gil Goobes; Eric Maimon; Dan Meyerstein

doi:https://doi.org/10.1039/c3dt51962g

Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Smadar Attia, Alexander Shames, Israel Zilbermann, Gil Goobes, Eric Maimon, Dan Meyerstein

Ben-Gurion University of the Negev, Bar-Ilan University, Ariel University

Research output: Contribution to journal › Article › peer-review

Abstract

Ni(ii)L², L² = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

Original language	American English
Pages (from-to)	103-110
Number of pages	8
Journal	Dalton Transactions
Volume	43
Issue number	1
DOIs	https://doi.org/10.1039/c3dt51962g
State	Published - 7 Jan 2014

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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Cite this

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abstract = "Ni(ii)L2, L2 = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.",

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AU - Maimon, Eric

AU - Meyerstein, Dan

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AB - Ni(ii)L2, L2 = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

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Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Abstract

All Science Journal Classification (ASJC) codes

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