Abstract
We propose a phase space method to propagate a quantum wavepacket driven by a strong external field. The method employs the periodic von Neumann basis with biorthogonal exchange recently introduced for the calculation of the energy eigenstates of time-independent quantum systems [A. Shimshovitz and D. J. Tannor, Phys. Rev. Lett. (in press) [e-print arXiv:1201.2299v1]]. While the individual elements in this basis set are time-independent, a small subset is chosen in a time-dependent manner to adapt to the evolution of the wavepacket in phase space. We demonstrate the accuracy and efficiency of the present propagation method by calculating the electronic wavepacket in a one-dimensional soft-core atom interacting with a superposition of an intense, few-cycle, near-infrared laser pulse and an attosecond extreme-ultraviolet laser pulse.
| Original language | English |
|---|---|
| Article number | 011102 |
| Journal | Journal of Chemical Physics |
| Volume | 137 |
| Issue number | 1 |
| DOIs | |
| State | Published - 7 Jul 2012 |
All Science Journal Classification (ASJC) codes
- General Physics and Astronomy
- Physical and Theoretical Chemistry
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