Comment on oxygen solubility measurements in non-aqueous electrolytes

Yair Ein-Eli; Alexander Kraytsberg

doi:https://doi.org/10.1149/1.3568818

Comment on oxygen solubility measurements in non-aqueous electrolytes

Yair Ein-Eli, Alexander Kraytsberg

Materials Science & Engineering

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

In this comment, we would like to highlight errors in recently published papers in Journal of Electrochemical Society, which contain the results on O₂ solubility in a series of non-aqueous electrolytes; the articles address the influence of this electrolyte property on the performance of Liair batteries. The effect of O₂ partition between the investigated electrolytes and the aqueous in-probe media had been neglected, though. This may be a source of substantial errors in determining O₂ solubility, and also may explain contradictions between reported works presenting data and values on O₂ solubility in non-aqueous electrolytes.

Original language	English
Pages (from-to)	S13
Journal	Journal of the Electrochemical Society
Volume	158
Issue number	5
DOIs	https://doi.org/10.1149/1.3568818
State	Published - 2011

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Materials Chemistry
Surfaces, Coatings and Films
Electrochemistry
Renewable Energy, Sustainability and the Environment

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abstract = "In this comment, we would like to highlight errors in recently published papers in Journal of Electrochemical Society, which contain the results on O2 solubility in a series of non-aqueous electrolytes; the articles address the influence of this electrolyte property on the performance of Liair batteries. The effect of O2 partition between the investigated electrolytes and the aqueous in-probe media had been neglected, though. This may be a source of substantial errors in determining O2 solubility, and also may explain contradictions between reported works presenting data and values on O2 solubility in non-aqueous electrolytes.",

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Comment on oxygen solubility measurements in non-aqueous electrolytes

Abstract

All Science Journal Classification (ASJC) codes

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