Combustion of energetic iodine-rich coordination polymer – Engineering of new biocidal materials

Ajay Kumar Chinnam; Avital Shlomovich; Olga Shamis; Nathan Petrutik; Dheeraj Kumar; Kangcai Wang; Eswaravara Prasadarao Komarala; Daniel Shem Tov; Muhamed Sućeska; Qi Long Yan; Michael Gozin

doi:10.1016/j.cej.2018.06.056

Combustion of energetic iodine-rich coordination polymer – Engineering of new biocidal materials

Ajay Kumar Chinnam, Avital Shlomovich, Olga Shamis, Nathan Petrutik, Dheeraj Kumar, Kangcai Wang, Eswaravara Prasadarao Komarala, Daniel Shem Tov, Muhamed Sućeska, Qi Long Yan, Michael Gozin

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

Development and molecular engineering of new highly-efficient energetic biocidal materials is a significant challenge and of a great importance. Until now this type of materials included mostly halogen-rich nano-thermites and iodine-rich organic materials. So far, no energetic coordination polymers were reported as precursors for combustion-generated biocidal agents. Here, we demonstrate for the first time the synthesis of uniquely-structured three-dimensional energetic coordination polymer (ECP3) containing Zn metal centers and iodine- and nitrogen-rich bridging ligand (2). Upon its combustion, ECP3 is capable of generating gaseous reactive iodine species and elemental iodine-coated ZnO particles. ECP3 presents a novel approach for the design of efficient biocidal agents.

Original language	English
Pages (from-to)	1084-1091
Number of pages	8
Journal	Chemical Engineering Journal
Volume	350
DOIs	https://doi.org/10.1016/j.cej.2018.06.056
State	Published - 15 Oct 2018

Keywords

Biocidal materials
Coordination polymers
Energetic materials

All Science Journal Classification (ASJC) codes

General Chemistry
Environmental Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1016/j.cej.2018.06.056

Cite this

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title = "Combustion of energetic iodine-rich coordination polymer – Engineering of new biocidal materials",

abstract = "Development and molecular engineering of new highly-efficient energetic biocidal materials is a significant challenge and of a great importance. Until now this type of materials included mostly halogen-rich nano-thermites and iodine-rich organic materials. So far, no energetic coordination polymers were reported as precursors for combustion-generated biocidal agents. Here, we demonstrate for the first time the synthesis of uniquely-structured three-dimensional energetic coordination polymer (ECP3) containing Zn metal centers and iodine- and nitrogen-rich bridging ligand (2). Upon its combustion, ECP3 is capable of generating gaseous reactive iodine species and elemental iodine-coated ZnO particles. ECP3 presents a novel approach for the design of efficient biocidal agents.",

keywords = "Biocidal materials, Coordination polymers, Energetic materials",

author = "{Kumar Chinnam}, Ajay and Avital Shlomovich and Olga Shamis and Nathan Petrutik and Dheeraj Kumar and Kangcai Wang and Komarala, {Eswaravara Prasadarao} and Tov, {Daniel Shem} and Muhamed Su{\'c}eska and Yan, {Qi Long} and Michael Gozin",

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year = "2018",

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doi = "10.1016/j.cej.2018.06.056",

language = "الإنجليزيّة",

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journal = "Chemical Engineering Journal",

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T1 - Combustion of energetic iodine-rich coordination polymer – Engineering of new biocidal materials

AU - Kumar Chinnam, Ajay

AU - Shlomovich, Avital

AU - Shamis, Olga

AU - Petrutik, Nathan

AU - Kumar, Dheeraj

AU - Wang, Kangcai

AU - Komarala, Eswaravara Prasadarao

AU - Tov, Daniel Shem

AU - Sućeska, Muhamed

AU - Yan, Qi Long

AU - Gozin, Michael

PY - 2018/10/15

Y1 - 2018/10/15

N2 - Development and molecular engineering of new highly-efficient energetic biocidal materials is a significant challenge and of a great importance. Until now this type of materials included mostly halogen-rich nano-thermites and iodine-rich organic materials. So far, no energetic coordination polymers were reported as precursors for combustion-generated biocidal agents. Here, we demonstrate for the first time the synthesis of uniquely-structured three-dimensional energetic coordination polymer (ECP3) containing Zn metal centers and iodine- and nitrogen-rich bridging ligand (2). Upon its combustion, ECP3 is capable of generating gaseous reactive iodine species and elemental iodine-coated ZnO particles. ECP3 presents a novel approach for the design of efficient biocidal agents.

AB - Development and molecular engineering of new highly-efficient energetic biocidal materials is a significant challenge and of a great importance. Until now this type of materials included mostly halogen-rich nano-thermites and iodine-rich organic materials. So far, no energetic coordination polymers were reported as precursors for combustion-generated biocidal agents. Here, we demonstrate for the first time the synthesis of uniquely-structured three-dimensional energetic coordination polymer (ECP3) containing Zn metal centers and iodine- and nitrogen-rich bridging ligand (2). Upon its combustion, ECP3 is capable of generating gaseous reactive iodine species and elemental iodine-coated ZnO particles. ECP3 presents a novel approach for the design of efficient biocidal agents.

KW - Biocidal materials

KW - Coordination polymers

KW - Energetic materials

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U2 - 10.1016/j.cej.2018.06.056

DO - 10.1016/j.cej.2018.06.056

M3 - مقالة

SN - 1385-8947

VL - 350

SP - 1084

EP - 1091

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

ER -

Combustion of energetic iodine-rich coordination polymer – Engineering of new biocidal materials

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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