Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

Longyang Dian; Ilan Marek

doi:10.1021/acs.orglett.0c01833

Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

Longyang Dian, Ilan Marek

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities.

Original language	English
Pages (from-to)	4914-4918
Number of pages	5
Journal	Organic Letters
Volume	22
Issue number	12
DOIs	https://doi.org/10.1021/acs.orglett.0c01833
State	Published - 19 Jun 2020

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/acs.orglett.0c01833

Cite this

@article{f36cf4e7c4384e8cb3b335679844539f,

title = "Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes",

abstract = "A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities. ",

author = "Longyang Dian and Ilan Marek",

note = "Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

year = "2020",

month = jun,

day = "19",

doi = "10.1021/acs.orglett.0c01833",

language = "الإنجليزيّة",

volume = "22",

pages = "4914--4918",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

AU - Dian, Longyang

AU - Marek, Ilan

PY - 2020/6/19

Y1 - 2020/6/19

N2 - A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities.

AB - A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities.

UR - http://www.scopus.com/inward/record.url?scp=85086747107&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.0c01833

DO - 10.1021/acs.orglett.0c01833

M3 - مقالة

SN - 1523-7060

VL - 22

SP - 4914

EP - 4918

JO - Organic Letters

JF - Organic Letters

IS - 12

ER -

Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this