Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes

Longyang Dian, Ilan Marek

Research output: Contribution to journalArticlepeer-review

Abstract

A mild diastereoselective and enantioselective cobalt-catalyzed hydrosilylation reaction of achiral cyclopropenes has been developed. In this protocol, various substituted cyclopropenes and arylsilanes were transformed, in the presence of readily available chiral cobalt complex, into silylcyclopropanes with high selectivities.

Original languageEnglish
Pages (from-to)4914-4918
Number of pages5
JournalOrganic Letters
Volume22
Issue number12
DOIs
StatePublished - 19 Jun 2020

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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