TY - JOUR
T1 - Chiral 2D Colloidal Semiconductor Quantum Wells
AU - Yang, Gaoling
AU - Kazes, Miri
AU - Oron, Dan
N1 - Financial support by the European Research Council consolidator grant ColloQuantO 681421, The Crown center of photonics and the Israeli Center of Research Excellence “Circle of Light” is gratefully acknowledged.
PY - 2018/7/11
Y1 - 2018/7/11
N2 - Induced chirality in colloidal semiconductor nanoparticles has raised significant attention in the past few years as an extremely sensitive spectroscopic tool and due to the promising applications of chiral quantum dots in sensing, quantum optics, and spintronics. Yet, the origin of the induced chiroptical effects in semiconductor nanoparticles is still not fully understood, partly because almost all the theoretical and experimental studies to date are based on the simple model system of a spherical nanocrystal. Here, the realization of induced chirality in atomically flat 2D colloidal quantum wells is shown. A strong circular dichroism (CD) response as well as an absorptive-like CD line shape is observed in chiral CdSe nanoplatelets (NPLs), significantly differing from that previously observed in spherical dots. Furthermore, this intense CD signal almost completely disappears after coating with a very thin CdS shell. In contrast, CdSe-CdS core-crown NPLs exhibit a spectral response which seems to originate independently from the core and the crown regions of the NPL. This work on the one hand further advances the understanding of the fundamental origin of induced chiroptical effects in semiconductor nanoparticles, and on the other opens a pathway toward applications using chiroptical materials.
AB - Induced chirality in colloidal semiconductor nanoparticles has raised significant attention in the past few years as an extremely sensitive spectroscopic tool and due to the promising applications of chiral quantum dots in sensing, quantum optics, and spintronics. Yet, the origin of the induced chiroptical effects in semiconductor nanoparticles is still not fully understood, partly because almost all the theoretical and experimental studies to date are based on the simple model system of a spherical nanocrystal. Here, the realization of induced chirality in atomically flat 2D colloidal quantum wells is shown. A strong circular dichroism (CD) response as well as an absorptive-like CD line shape is observed in chiral CdSe nanoplatelets (NPLs), significantly differing from that previously observed in spherical dots. Furthermore, this intense CD signal almost completely disappears after coating with a very thin CdS shell. In contrast, CdSe-CdS core-crown NPLs exhibit a spectral response which seems to originate independently from the core and the crown regions of the NPL. This work on the one hand further advances the understanding of the fundamental origin of induced chiroptical effects in semiconductor nanoparticles, and on the other opens a pathway toward applications using chiroptical materials.
UR - http://www.scopus.com/inward/record.url?scp=85047515350&partnerID=8YFLogxK
U2 - https://doi.org/10.1002/adfm.201802012
DO - https://doi.org/10.1002/adfm.201802012
M3 - مقالة
SN - 1616-301X
VL - 28
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 28
M1 - 1802012
ER -