Catalytic reduction of CO2 to CO by using zinc(II) and in situ generated carbodiphosphoranes

Roman Dobrovetsky; Douglas W. Stephan

doi:10.1002/anie.201208817

Catalytic reduction of CO₂ to CO by using zinc(II) and in situ generated carbodiphosphoranes

Research output: Contribution to journal › Article › peer-review

Abstract

Playing it 'CO'ol: CO₂ is catalytically reduced to CO with concurrent oxidation of phosphine to phosphineoxide by using an in situ generated catalyst derived from a carbodiphosphorane and zinc(II).

Original language	English
Pages (from-to)	2516-2519
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	9
DOIs	https://doi.org/10.1002/anie.201208817
State	Published - 25 Feb 2013
Externally published	Yes

Keywords

Lewis acid
phosphorus
reaction mechanisms
reduction
zinc

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/anie.201208817

Cite this

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title = "Catalytic reduction of CO2 to CO by using zinc(II) and in situ generated carbodiphosphoranes",

abstract = "Playing it 'CO'ol: CO2 is catalytically reduced to CO with concurrent oxidation of phosphine to phosphineoxide by using an in situ generated catalyst derived from a carbodiphosphorane and zinc(II).",

keywords = "Lewis acid, phosphorus, reaction mechanisms, reduction, zinc",

author = "Roman Dobrovetsky and Stephan, {Douglas W.}",

year = "2013",

month = feb,

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doi = "10.1002/anie.201208817",

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T1 - Catalytic reduction of CO2 to CO by using zinc(II) and in situ generated carbodiphosphoranes

AU - Dobrovetsky, Roman

AU - Stephan, Douglas W.

PY - 2013/2/25

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N2 - Playing it 'CO'ol: CO2 is catalytically reduced to CO with concurrent oxidation of phosphine to phosphineoxide by using an in situ generated catalyst derived from a carbodiphosphorane and zinc(II).

AB - Playing it 'CO'ol: CO2 is catalytically reduced to CO with concurrent oxidation of phosphine to phosphineoxide by using an in situ generated catalyst derived from a carbodiphosphorane and zinc(II).

KW - Lewis acid

KW - phosphorus

KW - reaction mechanisms

KW - reduction

KW - zinc

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U2 - 10.1002/anie.201208817

DO - 10.1002/anie.201208817

M3 - مقالة

SN - 1433-7851

VL - 52

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EP - 2519

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -