Carbon nanotube growth on AlN support: Comparison between Ni and Fe chemical states and morphology

Baran Eren, Laurent Marot, Roland Steiner, Teresa De Los Arcos, Marcel Düggelin, Daniel Mathys, Kenneth N. Goldie, Vesna Olivieri, Ernst Meyer

Research output: Contribution to journalArticlepeer-review

Abstract

In this work, carbon nanotubes (CNTs) are grown from Ni and Fe nanoparticles supported on a rough AlN surface. Although, identical experimental parameters are used during dewetting (island formation) via thermal treatment, Ni particles appear metallic and larger, whereas Fe particles are smaller and slightly oxidized. This difference in the nanoparticle chemical state and morphology reflects to CNTs during catalytic chemical vapor deposition in terms of their CNT growth mode and size: tip-growth mode for Ni catalyst with CNT diameters of up to 40 nm, whereas base-growth mode for Fe with CNT diameters typically less than 10 nm are observed.

Original languageEnglish
Pages (from-to)82-87
Number of pages6
JournalChemical Physics Letters
Volume609
DOIs
StatePublished - 5 Aug 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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