Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy

Ilse K. van Ravenhorst; Charlotte Vogt; Heiko Oosterbeek; Koen W. Bossers; José G. Moya-Cancino; Alexander P. van Bavel; Ad M.J. van der Eerden; David Vine; Frank M.F. de Groot; Florian Meirer; Bert M. Weckhuysen

doi:https://doi.org/10.1002/anie.201806354

Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy

Ilse K. van Ravenhorst, Charlotte Vogt, Heiko Oosterbeek, Koen W. Bossers, José G. Moya-Cancino, Alexander P. van Bavel, Ad M.J. van der Eerden, David Vine, Frank M.F. de Groot, Florian Meirer, Bert M. Weckhuysen

Research output: Contribution to journal › Article › peer-review

Abstract

A state-of-the-art operando spectroscopic technique is applied to Co/TiO₂ catalysts, which account for nearly half of the world's transportation fuels produced by Fischer–Tropsch catalysis. This allows determination of, at a spatial resolution of approximately 50 nm, the interdependence of formed hydrocarbon species in the inorganic catalyst. Observed trends show intra- and interparticular heterogeneities previously believed not to occur in particles under 200 μm. These heterogeneities are strongly dependent on changes in H₂/CO ratio, but also on changes thereby induced on the Co and Ti valence states. We have captured the genesis of an active FTS particle over its propagation to steady-state operation, in which microgradients lead to the gradual saturation of the Co/TiO₂ catalyst surface with long chain hydrocarbons (i.e., organic film formation).

Original language	English
Pages (from-to)	11957-11962
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	37
DOIs	https://doi.org/10.1002/anie.201806354
State	Published - 10 Sep 2018
Externally published	Yes

Keywords

Fischer–Tropsch synthesis
X-ray microspectroscopy
chemical imaging
heterogeneous catalysis
nanoparticles

All Science Journal Classification (ASJC) codes

General Chemistry
Catalysis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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https://doi.org/10.1002/anie.201806354

Cite this

van Ravenhorst, I. K., Vogt, C., Oosterbeek, H., Bossers, K. W., Moya-Cancino, J. G., van Bavel, A. P., van der Eerden, A. M. J., Vine, D., de Groot, F. M. F., Meirer, F., & Weckhuysen, B. M. (2018). Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy. Angewandte Chemie - International Edition, 57(37), 11957-11962. https://doi.org/10.1002/anie.201806354

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title = "Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy",

abstract = "A state-of-the-art operando spectroscopic technique is applied to Co/TiO2 catalysts, which account for nearly half of the world's transportation fuels produced by Fischer–Tropsch catalysis. This allows determination of, at a spatial resolution of approximately 50 nm, the interdependence of formed hydrocarbon species in the inorganic catalyst. Observed trends show intra- and interparticular heterogeneities previously believed not to occur in particles under 200 μm. These heterogeneities are strongly dependent on changes in H2/CO ratio, but also on changes thereby induced on the Co and Ti valence states. We have captured the genesis of an active FTS particle over its propagation to steady-state operation, in which microgradients lead to the gradual saturation of the Co/TiO2 catalyst surface with long chain hydrocarbons (i.e., organic film formation).",

keywords = "Fischer–Tropsch synthesis, X-ray microspectroscopy, chemical imaging, heterogeneous catalysis, nanoparticles",

author = "{van Ravenhorst}, {Ilse K.} and Charlotte Vogt and Heiko Oosterbeek and Bossers, {Koen W.} and Moya-Cancino, {Jos{\'e} G.} and {van Bavel}, {Alexander P.} and {van der Eerden}, {Ad M.J.} and David Vine and {de Groot}, {Frank M.F.} and Florian Meirer and Weckhuysen, {Bert M.}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2018",

month = sep,

day = "10",

doi = "https://doi.org/10.1002/anie.201806354",

language = "الإنجليزيّة",

volume = "57",

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journal = "Angewandte Chemie - International Edition",

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van Ravenhorst, IK, Vogt, C, Oosterbeek, H, Bossers, KW, Moya-Cancino, JG, van Bavel, AP, van der Eerden, AMJ, Vine, D, de Groot, FMF, Meirer, F & Weckhuysen, BM 2018, 'Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy', Angewandte Chemie - International Edition, vol. 57, no. 37, pp. 11957-11962. https://doi.org/10.1002/anie.201806354

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T1 - Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy

AU - van Ravenhorst, Ilse K.

AU - Vogt, Charlotte

AU - Oosterbeek, Heiko

AU - Bossers, Koen W.

AU - Moya-Cancino, José G.

AU - van Bavel, Alexander P.

AU - van der Eerden, Ad M.J.

AU - Vine, David

AU - de Groot, Frank M.F.

AU - Meirer, Florian

AU - Weckhuysen, Bert M.

PY - 2018/9/10

Y1 - 2018/9/10

N2 - A state-of-the-art operando spectroscopic technique is applied to Co/TiO2 catalysts, which account for nearly half of the world's transportation fuels produced by Fischer–Tropsch catalysis. This allows determination of, at a spatial resolution of approximately 50 nm, the interdependence of formed hydrocarbon species in the inorganic catalyst. Observed trends show intra- and interparticular heterogeneities previously believed not to occur in particles under 200 μm. These heterogeneities are strongly dependent on changes in H2/CO ratio, but also on changes thereby induced on the Co and Ti valence states. We have captured the genesis of an active FTS particle over its propagation to steady-state operation, in which microgradients lead to the gradual saturation of the Co/TiO2 catalyst surface with long chain hydrocarbons (i.e., organic film formation).

AB - A state-of-the-art operando spectroscopic technique is applied to Co/TiO2 catalysts, which account for nearly half of the world's transportation fuels produced by Fischer–Tropsch catalysis. This allows determination of, at a spatial resolution of approximately 50 nm, the interdependence of formed hydrocarbon species in the inorganic catalyst. Observed trends show intra- and interparticular heterogeneities previously believed not to occur in particles under 200 μm. These heterogeneities are strongly dependent on changes in H2/CO ratio, but also on changes thereby induced on the Co and Ti valence states. We have captured the genesis of an active FTS particle over its propagation to steady-state operation, in which microgradients lead to the gradual saturation of the Co/TiO2 catalyst surface with long chain hydrocarbons (i.e., organic film formation).

KW - Fischer–Tropsch synthesis

KW - X-ray microspectroscopy

KW - chemical imaging

KW - heterogeneous catalysis

KW - nanoparticles

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U2 - https://doi.org/10.1002/anie.201806354

DO - https://doi.org/10.1002/anie.201806354

M3 - مقالة

C2 - 30070756

SN - 1433-7851

VL - 57

SP - 11957

EP - 11962

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy

Abstract

Keywords

All Science Journal Classification (ASJC) codes

UN SDGs

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