Breaking the passivity wall of metals: Exempli gratia non-aqueous Ti–air battery

Yasin Emre Durmus, Marcel Kaltenberg, Krzysztof Dzieciol, Maximilian Schalenbach, Danny Gelman, Boris Shvartsev, Hermann Tempel, Hans Kungl, Rüdiger A. Eichel, Yair Ein-Eli

Research output: Contribution to journalArticlepeer-review

Abstract

A new multivalent metal–air battery employing Titanium (Ti) as active material in EMIm(HF)2.3F room temperature ionic liquid electrolyte is introduced. Ti metal is highly attractive as it is a light metal that can possibly transfer up to 4 electrons. The electrochemical behavior of Ti is known for its passivity in various media. Here, we evaluated the electrochemistry of Ti in EMIm(HF)2.3F with potentiodynamic polarization and galvanostatic discharge experiments. Ti–air battery could successfully be operated under relatively high current densities (up to 0.75 mA cm−2) with an average cell voltage of 1–1.2 V, yielding up to a discharge capacity of 66 mAh cm−2. When its full potential is harvested, such a metal–battery holds a unique potential to be the only metal with 4 electrons transfer during its discharge.

Original languageEnglish
Article number141903
JournalChemical Engineering Journal
Volume461
DOIs
StatePublished - 1 Apr 2023

Keywords

  • Metal–air battery
  • Non-aqueous electrolyte
  • Passivity
  • Titanium–air

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering
  • Environmental Chemistry

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