TY - JOUR
T1 - Bacteriorhodopsin/Ag nanoparticle-based hybrid nano-bio electrocatalyst for efficient and robust H2 evolution from water
AU - Zhao, Zhenlu
AU - Wang, Ping
AU - Xu, Xiaolong
AU - Sheves, Mordechai
AU - Jin, Yongdong
N1 - Publisher Copyright: © 2015 American Chemical Society.
PY - 2015/3/4
Y1 - 2015/3/4
N2 - Searching for novel hybrid electrocatalysts with high activity and strong durability for a direct electrochemical hydrogen evolution reaction (HER) is extremely desirable but still remains a significant challenge. Herein, we report a novel solid carbon cloth-supported hybrid nano-bio electrocatalyst, decorated with Ag nanoparticles and proton-pumping bacteriorhodopsin (bR) (Ag/bR/CP) that were prepared by in situ electroless deposition and vesicle fusion technology, respectively. When applied as a hydrogen evolution cathode, the Ag/bR/CP shows a low onset overpotential of 63 mV, good durability (no detectable change in its catalytic activity for up to 1000 cycles in alkaline media), and enhanced HER performance under 550 nm irradiation, attributed to the activation of Ag and synergistic effects following light absorption, demonstrated by photoelectrochemical measurements.
AB - Searching for novel hybrid electrocatalysts with high activity and strong durability for a direct electrochemical hydrogen evolution reaction (HER) is extremely desirable but still remains a significant challenge. Herein, we report a novel solid carbon cloth-supported hybrid nano-bio electrocatalyst, decorated with Ag nanoparticles and proton-pumping bacteriorhodopsin (bR) (Ag/bR/CP) that were prepared by in situ electroless deposition and vesicle fusion technology, respectively. When applied as a hydrogen evolution cathode, the Ag/bR/CP shows a low onset overpotential of 63 mV, good durability (no detectable change in its catalytic activity for up to 1000 cycles in alkaline media), and enhanced HER performance under 550 nm irradiation, attributed to the activation of Ag and synergistic effects following light absorption, demonstrated by photoelectrochemical measurements.
UR - http://www.scopus.com/inward/record.url?scp=84924301205&partnerID=8YFLogxK
U2 - https://doi.org/10.1021/jacs.5b00200
DO - https://doi.org/10.1021/jacs.5b00200
M3 - مقالة
SN - 0002-7863
VL - 137
SP - 2840
EP - 2843
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 8
ER -