Atrazine degradation through PEI-copper nanoparticles deposited onto montmorillonite and sand

We present the synthesis of new composite materials based on copper nanoparticles (Cu NPs) deposited onto montmorillonite (MK10) and quartz sand, for degradation of atrazine, in the context of an advanced oxidation process (AOP). The synthesis involves a first step in which polyethylenimine (PEI) capped Cu NPs (PEI-Cu NPs) are prepared, and then deposited onto, separately, MK10 and sand, through a solvent impregnation method. The resulting products are characterized in detail; the copper is found to exist as a mixture of copper (I, II) oxide. The degradation of atrazine follows a second-order kinetic model with constant values of K₂ = 1.7957 g mg^-1 min^-1 for MK10-PEI-Cu NPs and K₂ = 0.8133 g mg^-1 min^-1 for sand-PEI-Cu NPs. The reaction rate is linked to Cu₂O and CuO redox-active species within the layers, pores and surface of the host materials. A degradation mechanism is found with application of these composite materials in the presence of H₂O₂; adsorption occurs in the absence of H₂O₂. In contrast, the unmodified MK10 and sand exhibit adsorption in both of the above reaction conditions. Finally, the stability of the Cu NPs following degradation is evaluated, and no significant amount of copper leaching is found.