Asymmetric transfer hydrogenation of ketones catalyzed by rhodium block copolymer complexes in aqueous micelles

Shlomi Elias; Kerem Goren; Arkadi Vigalok

doi:10.1055/s-0032-1317487

Asymmetric transfer hydrogenation of ketones catalyzed by rhodium block copolymer complexes in aqueous micelles

Shlomi Elias, Kerem Goren, Arkadi Vigalok

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

High activity and enantioselectivity were achieved in the rhodium-catalyzed asymmetric transfer-hydrogenation reactions of ketones in pure water using a novel amphiphilic block polypeptide ligand. The covalent linkage of the catalyst to the block copolymer plays a significant role and provides higher conversions and better recyclability than regular micellar or nonmicellar systems.

Original language	English
Pages (from-to)	2619-2622
Number of pages	4
Journal	Synlett
Volume	23
Issue number	18
DOIs	https://doi.org/10.1055/s-0032-1317487
State	Published - 2012

Keywords

asymmetric transfer hydrogenation
block copolymers
ketones
micellar catalysis
rhodium

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-0032-1317487

Cite this

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title = "Asymmetric transfer hydrogenation of ketones catalyzed by rhodium block copolymer complexes in aqueous micelles",

abstract = "High activity and enantioselectivity were achieved in the rhodium-catalyzed asymmetric transfer-hydrogenation reactions of ketones in pure water using a novel amphiphilic block polypeptide ligand. The covalent linkage of the catalyst to the block copolymer plays a significant role and provides higher conversions and better recyclability than regular micellar or nonmicellar systems.",

keywords = "asymmetric transfer hydrogenation, block copolymers, ketones, micellar catalysis, rhodium",

author = "Shlomi Elias and Kerem Goren and Arkadi Vigalok",

year = "2012",

doi = "10.1055/s-0032-1317487",

language = "الإنجليزيّة",

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AU - Elias, Shlomi

AU - Goren, Kerem

AU - Vigalok, Arkadi

PY - 2012

Y1 - 2012

N2 - High activity and enantioselectivity were achieved in the rhodium-catalyzed asymmetric transfer-hydrogenation reactions of ketones in pure water using a novel amphiphilic block polypeptide ligand. The covalent linkage of the catalyst to the block copolymer plays a significant role and provides higher conversions and better recyclability than regular micellar or nonmicellar systems.

AB - High activity and enantioselectivity were achieved in the rhodium-catalyzed asymmetric transfer-hydrogenation reactions of ketones in pure water using a novel amphiphilic block polypeptide ligand. The covalent linkage of the catalyst to the block copolymer plays a significant role and provides higher conversions and better recyclability than regular micellar or nonmicellar systems.

KW - asymmetric transfer hydrogenation

KW - block copolymers

KW - ketones

KW - micellar catalysis

KW - rhodium

UR - http://www.scopus.com/inward/record.url?scp=84867560399&partnerID=8YFLogxK

U2 - 10.1055/s-0032-1317487

DO - 10.1055/s-0032-1317487

M3 - مقالة

SN - 0936-5214

VL - 23

SP - 2619

EP - 2622

JO - Synlett

JF - Synlett

IS - 18

ER -

Asymmetric transfer hydrogenation of ketones catalyzed by rhodium block copolymer complexes in aqueous micelles

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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