An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions

Anat Milo; Ronny Neumann

doi:https://doi.org/10.1039/c0cc04205f

An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions

Anat Milo, Ronny Neumann

Department of Molecular Chemistry and Materials Science

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

Abstract

An insoluble, porous, amorphous, homochiral material based on a polypeptide titanium–phosphonate scaffold with an encapsulated achiral Mn^III–salen was prepared and characterized. Consecutive epoxidation and hydration of styrene and its derivatives by aqueous hypochlorite in THF showed the highly enantioselective (>99%) formation of styrene diol derivatives.

Original language	American English
Pages (from-to)	2535-2537
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	9
DOIs	https://doi.org/10.1039/c0cc04205f
State	Published - 14 Feb 2011

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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title = "An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions",

abstract = "An insoluble, porous, amorphous, homochiral material based on a polypeptide titanium–phosphonate scaffold with an encapsulated achiral MnIII–salen was prepared and characterized. Consecutive epoxidation and hydration of styrene and its derivatives by aqueous hypochlorite in THF showed the highly enantioselective (>99%) formation of styrene diol derivatives.",

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AU - Milo, Anat

AU - Neumann, Ronny

PY - 2011/2/14

Y1 - 2011/2/14

N2 - An insoluble, porous, amorphous, homochiral material based on a polypeptide titanium–phosphonate scaffold with an encapsulated achiral MnIII–salen was prepared and characterized. Consecutive epoxidation and hydration of styrene and its derivatives by aqueous hypochlorite in THF showed the highly enantioselective (>99%) formation of styrene diol derivatives.

AB - An insoluble, porous, amorphous, homochiral material based on a polypeptide titanium–phosphonate scaffold with an encapsulated achiral MnIII–salen was prepared and characterized. Consecutive epoxidation and hydration of styrene and its derivatives by aqueous hypochlorite in THF showed the highly enantioselective (>99%) formation of styrene diol derivatives.

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U2 - https://doi.org/10.1039/c0cc04205f

DO - https://doi.org/10.1039/c0cc04205f

M3 - Article

C2 - 21225044

SN - 1359-7345

VL - 47

SP - 2535

EP - 2537

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions

Abstract

All Science Journal Classification (ASJC) codes

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