A self-catalyzed reaction of 1,2-dibenzoyl-: O-carborane with hydrosilanes-formation of new hydrofuranes

Kuldeep Jaiswal; Solomon Volodarsky; Vladimir Kampel; Roman Dobrovetsky

doi:10.1039/c9cc04780h

A self-catalyzed reaction of 1,2-dibenzoyl-: O-carborane with hydrosilanes-formation of new hydrofuranes

Kuldeep Jaiswal, Solomon Volodarsky, Vladimir Kampel, Roman Dobrovetsky

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

The activation of Si-H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si-H bonds, yielding new hydrofurane-type products. The mechanism of this Si-H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.

Original language	English
Pages (from-to)	10448-10451
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	70
DOIs	https://doi.org/10.1039/c9cc04780h
State	Published - 2019

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/c9cc04780h

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title = "A self-catalyzed reaction of 1,2-dibenzoyl-: O-carborane with hydrosilanes-formation of new hydrofuranes",

abstract = "The activation of Si-H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si-H bonds, yielding new hydrofurane-type products. The mechanism of this Si-H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.",

author = "Kuldeep Jaiswal and Solomon Volodarsky and Vladimir Kampel and Roman Dobrovetsky",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

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AU - Volodarsky, Solomon

AU - Kampel, Vladimir

AU - Dobrovetsky, Roman

PY - 2019

Y1 - 2019

N2 - The activation of Si-H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si-H bonds, yielding new hydrofurane-type products. The mechanism of this Si-H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.

AB - The activation of Si-H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si-H bonds, yielding new hydrofurane-type products. The mechanism of this Si-H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.

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U2 - 10.1039/c9cc04780h

DO - 10.1039/c9cc04780h

M3 - مقالة

SN - 1359-7345

VL - 55

SP - 10448

EP - 10451

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

A self-catalyzed reaction of 1,2-dibenzoyl-: O-carborane with hydrosilanes-formation of new hydrofuranes

Abstract

All Science Journal Classification (ASJC) codes

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