TY - JOUR
T1 - A review of wetting versus adsorption, complexions, and related phenomena
T2 - The rosetta stone of wetting
AU - Kaplan, Wayne D.
AU - Chatain, Dominique
AU - Wynblatt, Paul
AU - Carter, W. Craig
N1 - Funding Information: Acknowledgements We would like to thank our students who critically reviewed this paper: R. Zucker and G. Atiya. We thank R. Zucker for contributing to Panel 2. We also acknowledge the staff of the Best Western in Cassis, France, who showed unending patience when we descended upon their lobby for an entire week to consolidate this review. The effort leading to this review received funding from the European Community’s Seventh Framework Programme (FP7/ 2007-2013) under grant agreement FP7-NMP-2009-CSA-233484— MACAN (Merging Atomistic and Continuum Analysis of Nanometer Length-Scale Metal-Oxide Systems for Energy and Catalysis Applications).
PY - 2013/9
Y1 - 2013/9
N2 - This paper reviews the fundamental concepts and the terminology of wetting. In particular, it focuses on high temperature wetting phenomena of primary interest to materials scientists. We have chosen to split this review into two sections: one related to macroscopic (continuum) definitions and the other to a microscopic (or atomistic) approach, where the role of chemistry and structure of interfaces and free surfaces on wetting phenomena are addressed. A great deal of attention has been placed on thermodynamics. This allows clarification of many important features, including the state of equilibrium between phases, the kinetics of equilibration, triple lines, hysteresis, adsorption (segregation) and the concept of complexions, intergranular films, prewetting, bulk phase transitions versus "interface transitions", liquid versus solid wetting, and wetting versus dewetting.
AB - This paper reviews the fundamental concepts and the terminology of wetting. In particular, it focuses on high temperature wetting phenomena of primary interest to materials scientists. We have chosen to split this review into two sections: one related to macroscopic (continuum) definitions and the other to a microscopic (or atomistic) approach, where the role of chemistry and structure of interfaces and free surfaces on wetting phenomena are addressed. A great deal of attention has been placed on thermodynamics. This allows clarification of many important features, including the state of equilibrium between phases, the kinetics of equilibration, triple lines, hysteresis, adsorption (segregation) and the concept of complexions, intergranular films, prewetting, bulk phase transitions versus "interface transitions", liquid versus solid wetting, and wetting versus dewetting.
UR - http://www.scopus.com/inward/record.url?scp=84879911920&partnerID=8YFLogxK
U2 - 10.1007/s10853-013-7462-y
DO - 10.1007/s10853-013-7462-y
M3 - مقالة مرجعية
SN - 0022-2461
VL - 48
SP - 5681
EP - 5717
JO - Journal of Materials Science
JF - Journal of Materials Science
IS - 17
ER -