A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application

Zinovi Dashevsky, Sergii Mamykin, Bohdan Dzundza, Mark Auslender, Roni Z. Shneck

Research output: Contribution to journalReview articlepeer-review

Abstract

Submicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coefficient of lead chalcogenide films is attributed to a potential relief that is built along the grain boundaries. It scatters charge carriers with low energy and does not affect carriers with higher energy. The model that accounts for the thermoelectric properties of the films is described and assessed experimentally. The application of a flexible thermoelectric device (module) based on the nanocrystalline film thermoelectric semiconductors as high sensitivity radiation detectors is suggested.

Original languageAmerican English
Article number3774
JournalEnergies
Volume16
Issue number9
DOIs
StatePublished - 1 May 2023

Keywords

  • figure of merit
  • film thermoelectric module
  • nanostructuring
  • thermoelectric materials

All Science Journal Classification (ASJC) codes

  • Control and Optimization
  • Energy (miscellaneous)
  • Engineering (miscellaneous)
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering
  • Fuel Technology
  • Renewable Energy, Sustainability and the Environment

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