A regioselective huisgen reaction inside a keplerate polyoxomolybdate nanoreactor

Claire Besson; Sebastian Schmitz; Kimberly M. Capella; Sivil Kopilevich; Ira A. Weinstock; Paul Kögerler

doi:10.1039/c2dt30502j

A regioselective huisgen reaction inside a keplerate polyoxomolybdate nanoreactor

Claire Besson, Sebastian Schmitz, Kimberly M. Capella, Sivil Kopilevich, Ira A. Weinstock, Paul Kögerler

Department of Chemistry

Ben-Gurion University of the Negev

Research output: Contribution to journal › Article › peer-review

Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a (Mo₁₃₂)-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

Original language	American English
Pages (from-to)	9852-9854
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	41
Issue number	33
DOIs	https://doi.org/10.1039/c2dt30502j
State	Published - 31 Jul 2012

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1039/c2dt30502j

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abstract = "A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a (Mo132)-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.",

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AU - Weinstock, Ira A.

AU - Kögerler, Paul

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AB - A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a (Mo132)-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

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JF - Journal of the Chemical Society. Dalton Transactions

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A regioselective huisgen reaction inside a keplerate polyoxomolybdate nanoreactor

Abstract

All Science Journal Classification (ASJC) codes

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