A highly versatile fluorenone-based macrocycle for the sensitive detection of polycyclic aromatic hydrocarbons and fluoride anions

Ingrid Suzy Tamgho; Sauradip Chaudhuri; Molly Verderame; Dana J. DiScenza; Mindy Levine

doi:10.1039/c7ra05404a

A highly versatile fluorenone-based macrocycle for the sensitive detection of polycyclic aromatic hydrocarbons and fluoride anions

Ingrid Suzy Tamgho
, Sauradip Chaudhuri
, Molly Verderame
, Dana J. DiScenza
, Mindy Levine

Research output: Contribution to journal › Article › peer-review

Abstract

Reported herein is the high yielding synthesis of a new fluorenone-based triazolophane and its sensing capabilities for polycyclic aromatic hydrocarbons (PAHs) and fluoride anions. Fluorescence, UV/Vis and ¹H NMR spectroscopy results showed the triazolophane has a high sensitivity for selected PAHs and binds the fluoride anion in a 2:1 stoichiometry via C-H hydrogen bonding with the triazole and fluorenone protons.

Original language	English
Pages (from-to)	28489-28493
Number of pages	5
Journal	RSC Advances
Volume	7
Issue number	45
DOIs	https://doi.org/10.1039/c7ra05404a
State	Published - 2017
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1039/c7ra05404a

Cite this

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title = "A highly versatile fluorenone-based macrocycle for the sensitive detection of polycyclic aromatic hydrocarbons and fluoride anions",

abstract = "Reported herein is the high yielding synthesis of a new fluorenone-based triazolophane and its sensing capabilities for polycyclic aromatic hydrocarbons (PAHs) and fluoride anions. Fluorescence, UV/Vis and 1H NMR spectroscopy results showed the triazolophane has a high sensitivity for selected PAHs and binds the fluoride anion in a 2:1 stoichiometry via C-H hydrogen bonding with the triazole and fluorenone protons.",

author = "Tamgho, \{Ingrid Suzy\} and Sauradip Chaudhuri and Molly Verderame and DiScenza, \{Dana J.\} and Mindy Levine",

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year = "2017",

doi = "10.1039/c7ra05404a",

language = "English",

volume = "7",

pages = "28489--28493",

journal = "RSC Advances",

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publisher = "Royal Society of Chemistry",

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AU - Tamgho, Ingrid Suzy

AU - Chaudhuri, Sauradip

AU - Verderame, Molly

AU - DiScenza, Dana J.

AU - Levine, Mindy

PY - 2017

Y1 - 2017

N2 - Reported herein is the high yielding synthesis of a new fluorenone-based triazolophane and its sensing capabilities for polycyclic aromatic hydrocarbons (PAHs) and fluoride anions. Fluorescence, UV/Vis and 1H NMR spectroscopy results showed the triazolophane has a high sensitivity for selected PAHs and binds the fluoride anion in a 2:1 stoichiometry via C-H hydrogen bonding with the triazole and fluorenone protons.

AB - Reported herein is the high yielding synthesis of a new fluorenone-based triazolophane and its sensing capabilities for polycyclic aromatic hydrocarbons (PAHs) and fluoride anions. Fluorescence, UV/Vis and 1H NMR spectroscopy results showed the triazolophane has a high sensitivity for selected PAHs and binds the fluoride anion in a 2:1 stoichiometry via C-H hydrogen bonding with the triazole and fluorenone protons.

UR - https://www.scopus.com/pages/publications/85021692629

U2 - 10.1039/c7ra05404a

DO - 10.1039/c7ra05404a

M3 - Article

SN - 2046-2069

VL - 7

SP - 28489

EP - 28493

JO - RSC Advances

JF - RSC Advances

IS - 45

ER -

A highly versatile fluorenone-based macrocycle for the sensitive detection of polycyclic aromatic hydrocarbons and fluoride anions

Abstract

ASJC Scopus subject areas

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