A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

Bin Wang; Tan Phat Huynh; Weiwei Wu; Naseem Hayek; Thu Trang Do; John C. Cancilla; Jose S. Torrecilla; Masrur Morshed Nahid; John M. Colwell; Oz M. Gazit; Sreenivasa Reddy Puniredd; Christopher R. McNeill; Prashant Sonar; Hossam Haick

doi:10.1002/adma.201505641

A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

Bin Wang
, Tan Phat Huynh
, Weiwei Wu
, Naseem Hayek
, Thu Trang Do
, John C. Cancilla
, Jose S. Torrecilla
, Masrur Morshed Nahid
, John M. Colwell
, Oz M. Gazit
, Sreenivasa Reddy Puniredd
, Christopher R. McNeill
, Prashant Sonar
, Hossam Haick

Chemical Engineering

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.

Original language	English
Pages (from-to)	4012-4018
Number of pages	7
Journal	Advanced Materials
Volume	28
Issue number	21
DOIs	https://doi.org/10.1002/adma.201505641
State	Published - Jun 2016

Keywords

ambipolar
diketopyrrolopyrrole
isomers
sensors
xylene

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.201505641

Cite this

Wang, B., Huynh, T. P., Wu, W., Hayek, N., Do, T. T., Cancilla, J. C., Torrecilla, J. S., Nahid, M. M., Colwell, J. M., Gazit, O. M., Puniredd, S. R., McNeill, C. R., Sonar, P., & Haick, H. (2016). A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers. Advanced Materials, 28(21), 4012-4018. https://doi.org/10.1002/adma.201505641

@article{ffa0be3a51ab48038db767242a11b3cc,

title = "A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers",

abstract = "A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.",

keywords = "ambipolar, diketopyrrolopyrrole, isomers, sensors, xylene",

author = "Bin Wang and Huynh, \{Tan Phat\} and Weiwei Wu and Naseem Hayek and Do, \{Thu Trang\} and Cancilla, \{John C.\} and Torrecilla, \{Jose S.\} and Nahid, \{Masrur Morshed\} and Colwell, \{John M.\} and Gazit, \{Oz M.\} and Puniredd, \{Sreenivasa Reddy\} and McNeill, \{Christopher R.\} and Prashant Sonar and Hossam Haick",

note = "Funding Information: C.R.M. acknowledges support from the Australian Research Council (DP130102616). Part of this research was undertaken on the SAXS/WAXS beamline at the Australian Synchrotron, Victoria, Australia. C.R.M. and M.M.N. thank Dr. Eliot Gann for assistance with GIWAXS measurements and data analysis. T.T.D., J.C., and P.S. wish to thank the CRC for Polymers at Queensland University of Technology (QUT) for equipment support. P.S. also acknowledges financial support from the Australian Research Council (Grant No. FT130101337).",

year = "2016",

month = jun,

doi = "10.1002/adma.201505641",

language = "English",

volume = "28",

pages = "4012--4018",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "John Wiley and Sons Inc.",

number = "21",

}

Wang, B, Huynh, TP, Wu, W, Hayek, N, Do, TT, Cancilla, JC, Torrecilla, JS, Nahid, MM, Colwell, JM, Gazit, OM, Puniredd, SR, McNeill, CR, Sonar, P & Haick, H 2016, 'A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers', Advanced Materials, vol. 28, no. 21, pp. 4012-4018. https://doi.org/10.1002/adma.201505641

TY - JOUR

T1 - A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

AU - Wang, Bin

AU - Huynh, Tan Phat

AU - Wu, Weiwei

AU - Hayek, Naseem

AU - Do, Thu Trang

AU - Cancilla, John C.

AU - Torrecilla, Jose S.

AU - Nahid, Masrur Morshed

AU - Colwell, John M.

AU - Gazit, Oz M.

AU - Puniredd, Sreenivasa Reddy

AU - McNeill, Christopher R.

AU - Sonar, Prashant

AU - Haick, Hossam

N1 - Funding Information: C.R.M. acknowledges support from the Australian Research Council (DP130102616). Part of this research was undertaken on the SAXS/WAXS beamline at the Australian Synchrotron, Victoria, Australia. C.R.M. and M.M.N. thank Dr. Eliot Gann for assistance with GIWAXS measurements and data analysis. T.T.D., J.C., and P.S. wish to thank the CRC for Polymers at Queensland University of Technology (QUT) for equipment support. P.S. also acknowledges financial support from the Australian Research Council (Grant No. FT130101337).

PY - 2016/6

Y1 - 2016/6

N2 - A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.

AB - A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.

KW - ambipolar

KW - diketopyrrolopyrrole

KW - isomers

KW - sensors

KW - xylene

UR - https://www.scopus.com/pages/publications/84962505697

U2 - 10.1002/adma.201505641

DO - 10.1002/adma.201505641

M3 - Article

SN - 0935-9648

VL - 28

SP - 4012

EP - 4018

JO - Advanced Materials

JF - Advanced Materials

IS - 21

ER -

A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

Abstract

Keywords

ASJC Scopus subject areas

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