(±)-4,12,15,18,26-pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0 3,14.04,12.06,11.018,26.0 19,24]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione methanol disolvate

Maayan Gil; Joseph Almog; Faina Dubnikova; Benny Bogoslavski; Shmuel Cohen

doi:10.1107/S1600536814006643

(±)-4,12,15,18,26-pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0 ^3,14.0^4,12.0^6,11.0^18,26.0 ^19,24]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione methanol disolvate

Maayan Gil, Joseph Almog, Faina Dubnikova, Benny Bogoslavski, Shmuel Cohen

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C₂₄H₁₄O₉· 2CH₃OH, displays a chair-shaped form. The two dihydroindenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of dihydroindenone ring systems and the mean plane of central fused-ring system are 67.91(5) and 73.52(4)°, respectively. In the crystal, extensive O - H⋯O hydrogen bonds, weak C - H⋯O hydrogen bonds and C - H⋯π interactions link the molecules into a three-dimensional supramolecular architecture.

Original language	English
Pages (from-to)	o506
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	5
DOIs	https://doi.org/10.1107/S1600536814006643
State	Published - May 2014

Keywords

R factor = 0.067
T = 295 K
data-to-parameter ratio = 16.1
mean σ(C-C) = 0.004 A°
single-crystal X-ray study
wR factor = 0.153

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536814006643

Cite this

@article{7c3b32b7ed734bb7830e19afc171f918,

title = "(±)-4,12,15,18,26-pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0 3,14.04,12.06,11.018,26.0 19,24]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione methanol disolvate",

abstract = "The title compound, C24H14O9· 2CH3OH, displays a chair-shaped form. The two dihydroindenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of dihydroindenone ring systems and the mean plane of central fused-ring system are 67.91(5) and 73.52(4)°, respectively. In the crystal, extensive O - H⋯O hydrogen bonds, weak C - H⋯O hydrogen bonds and C - H⋯π interactions link the molecules into a three-dimensional supramolecular architecture.",

keywords = "R factor = 0.067, T = 295 K, data-to-parameter ratio = 16.1, mean σ(C-C) = 0.004 A°, single-crystal X-ray study, wR factor = 0.153",

author = "Maayan Gil and Joseph Almog and Faina Dubnikova and Benny Bogoslavski and Shmuel Cohen",

year = "2014",

month = may,

doi = "10.1107/S1600536814006643",

language = "الإنجليزيّة",

volume = "70",

pages = "o506",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "5",

}

(±)-4,12,15,18,26-pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0 ^3,14.0^4,12.0^6,11.0^18,26.0 ^19,24]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione methanol disolvate. / Gil, Maayan; Almog, Joseph; Dubnikova, Faina et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 5, 05.2014, p. o506.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - (±)-4,12,15,18,26-pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0 3,14.04,12.06,11.018,26.0 19,24]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione methanol disolvate

AU - Gil, Maayan

AU - Almog, Joseph

AU - Dubnikova, Faina

AU - Bogoslavski, Benny

AU - Cohen, Shmuel

PY - 2014/5

Y1 - 2014/5

N2 - The title compound, C24H14O9· 2CH3OH, displays a chair-shaped form. The two dihydroindenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of dihydroindenone ring systems and the mean plane of central fused-ring system are 67.91(5) and 73.52(4)°, respectively. In the crystal, extensive O - H⋯O hydrogen bonds, weak C - H⋯O hydrogen bonds and C - H⋯π interactions link the molecules into a three-dimensional supramolecular architecture.

AB - The title compound, C24H14O9· 2CH3OH, displays a chair-shaped form. The two dihydroindenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of dihydroindenone ring systems and the mean plane of central fused-ring system are 67.91(5) and 73.52(4)°, respectively. In the crystal, extensive O - H⋯O hydrogen bonds, weak C - H⋯O hydrogen bonds and C - H⋯π interactions link the molecules into a three-dimensional supramolecular architecture.

KW - R factor = 0.067

KW - T = 295 K

KW - data-to-parameter ratio = 16.1

KW - mean σ(C-C) = 0.004 A°

KW - single-crystal X-ray study

KW - wR factor = 0.153

UR - http://www.scopus.com/inward/record.url?scp=84899914862&partnerID=8YFLogxK

U2 - 10.1107/S1600536814006643

DO - 10.1107/S1600536814006643

M3 - مقالة

SN - 1600-5368

VL - 70

SP - o506

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -